xt7r7s7hqw6c https://exploreuk.uky.edu/dips/xt7r7s7hqw6c/data/mets.xml Moore, Philip North, b. 1849. 1877 books b96-12-34887795 English Stereotyped for the Survey by Major, Johnston & Barrett, Yeoman Press, : [Frankfort, Ky. : Contact the Special Collections Research Center for information regarding rights and use of this collection. Iron industry and trade Kentucky. Report upon the Airdrie furnace and property, Muhlenburg County, Kentucky / by P.N. Moore. text Report upon the Airdrie furnace and property, Muhlenburg County, Kentucky / by P.N. Moore. 1877 2002 true xt7r7s7hqw6c section xt7r7s7hqw6c GEOLOG(ICAL SURVEY OF KENTUCKY. N. S. SHALER, DIRECTOR. REPORT UPON THE AIRDRIE FURNACE AND PROPERTY, MUHLENBURG COUNTY, KENTUCKY, BY P. N. MOORE. PART IV. VOL. II. SECOND SERIES. VOL. II.-I I i6, & ,62 This page in the original text is blank. INTRODUCTORY LETTER. Professor N. S. SHALER, Director Kentucky Geological Survey: SIR: In accordance with your instructions, I made, during the past summer, an examination of the Airdrie Furnace and property, with a view to ascertain something of the resources of the estate, the causes of the former non-success of the furnace, and to suggest, if possible, the means whereby it can be brought into successful operation. The time at my com- mand did not suffice for a careful geological examination of the whole property, and my attention was therefore given only to that portion in the immediate neighborhood of the furnace. It is to this that the furnace must look for its supply of fuel for a long time to come, and, as on examination it proved suffi- ciently rich in coal to place the matter of a sufficient supply beyond reasonable doubt, little attention was given to any other part of the property. P. N. MOORE, Assistant. LEXINGTON, Ky., December, 1874. 063 REPORT UPON THE AIRDRIE FURNACE AND PROPERTY, MUHLENB3URG COUNTY, KY. SITUATION. Airdrie Furnace is situated near the village of Paradise, Muhlenburg county, Kentucky, on the bank of Green river, one hundred and thirty miles above its mouth, eighty-five miles below the head of slack-water navigation at Bowlifig Green. It is also four miles above Rockport, where the Lou- isville, Paducah and Southwestern Railroad crosses Green river, a stream which furnishes slack-water navigation for two hundred and fifteen miles, at nearly all times of the year, to boats drawing four feet of water; and during the greater portion of the time is navigable for boats drawing six feet. There are but two locks between Airdrie Furnace and the Ohio river, and these are of a size uniform on Green river- one hundred and forty-five feet long by thirty-six feet wide. THE FURNACE. The furnace was built in 1855-'56. It has an iron shell stack, resting upon a masonry base, twenty-six and a half feet square by twenty-one feet high. The outside diameter of the shell is twenty-three feet. The internal dimensions of the furnace are as follows: height fifty feet, diameter of bosh seventeen feet, height to bosh twenty-four feet (bosh cylindrical for six feet), diameter of throat eleven feet. The hearth is four feet high (elliptica in shape), seven feet four inches by (about) five feet. "4 AIRDRIE FURNACE AND PROPERTY. The furnace is entirely open-topped, having no facilities for saving the gases, and requiring separate firing for both boil- ers and hot-blast. There are two hot-blast ovens of the old-fashioned pistol- pipe pattern, with thirty-four pipes in each oven, ten curved pipes on each side, with seven straight at each end. The pipes are eight feet long, elliptical in cross section, nine by eighteen inches, with diaphragm through the center of each. There are four boilers, each forty inches in diameter by twenty-eight feet in length, each boiler having two flues. The engine is vertical, with direct connection between the steam and blast cylinders, and also connected with a heavy walking beam and fly-wheel, the walking beam working with a counterpoise at one end. The steam cylinder is twenty inches in diameter, and nine feet stroke; the blast cylinder six feet ten inches in diameter, stroke same as steam cylinder. The engine-house is a splendid stone structure, built of a fine free stone, which occurs at the furnace. Everything about the furnace is constructed in the most thorough and durable manner. The top of the furnace is about the level of the No. ii Coal, to be hereafter described, and the ore and coal from the No. 12 seam were brought to the furnace mouth through a tunnel cut in the No. r l Coal. The engine is in good order and well preserved. The furnace proper stands perfectly sound, and could, in a very brief time, be put in condition to go into blast; but among the buildings attached thereto the lapse of the many years since they were in use has not been without its effect, so that repairs to both buildings arid hot-blast apparatus will need to be made before they can be used again. THE PROPERTY. The Airdrie Furnace property consists of about 17,ooo acres of land in Muhlenburg county, Kentucky. This land is not all in one body, but lies in various sized lots, ranging from 500 to i6S S REPORT UPON THE 5,ooo acres. The greater portion of the estate lies within a short distance of the furnace; but one tract of about 5,000 acres-the old Buckner Furnace property-is about five miles from Greenville, the county seat of Muhlenburg county, and fifteen miles from Airdrie. Upon this tract, if all reports be true, there are extensive beds of iron ore, as well as some of the lower coals, one of which, said to be four feet thick, was mined and coked for use at the old Buckner Furnace. The situation is such, however, being five miles from the railroad at Greenville, that for the present, at least, the minerals of this tract cannot be rendered available. We come then to the examination of the property adjacent to the furnace. A geological section showing the number and position of the coals here is given in the third volume of the Kentucky Geological Reports, first series, page 24. This section was obtained in sinking a shaft at the furnace, and the measurements are therefore probably much more accu- rate than those usually obtained by boring. In reproducing the essential parts of the section, and describing the coals, the numbers assigned to them in the first series Geological Survey Reports will be used provisionally, for the reason that they are best known by these numbers, and that, although they have been discarded by the present Survey, the final nomenclature has not yet been decided upon. We have, then, at this place the following coals: 1. Coal No. I2, two feet thickness of clear coal, then two feet of brashy coal. Resting upon this is a bed of slaty car- bonate of iron, which sometimes contains a small amount of carbonaceous matter, and is called a Black-band iron ore. This ore ranges from four to fourteen inches in thickness, with an average of perhaps five or six. Its chemical consti- tution will be referred to hereafter. II. Twenty-one feet below Coal No. 12, resting immediately under a hard, blue limestone, is Coal No. i i, six feet thick, in three members, each about two feet in thickness, with a part- ing of one to two inches of pyritiferous shale between each member. This coal is about sixty-five feet above Green river. i66 6 AIRDRIE FURNACE AND PROPERTY. III. Below the level of Green river, and eighty-four feet under Coal No. I I, is Coal No. 9, five feet thick. This is the same coal as that mined so extensively for the Louisville market along the line of the Louisville, Paducah and South- western Railroad. Little is known of its quality here, but it is safe to suppose that it does not vary greatly from that along the railroad. IV. There are one or two thin coals below this, but it is not until a depth of three hundred and forty-one feet below No. 9 is reached that another coal of workable thickness occurs. This is called No. 5 by Dr. Owen, and is three feet six inches thick. If the report of the miners who sunk the shaft, and of others who were employed at the furnace, is to be believed, this coal is of most excellent quality. A drift was run, and considerable coal taken out and used under the boilers with great success. We see, therefore, that there are here, including the No. 12 Coal, which can be profitably worked with the overlying iron ore, no less than four coals of workable thickness. QUALITY OF THE COAL. Of the quality of No. 5 and No. 9 Coal at this place, we of course know nothing, for it was impossible to obtain samples for analysis. Samples of the No. II coal were obtained from the mine at Paradise, adjoining the Airdrie property. They were taken with gteat care from a number of rooms in the mine, in order to obtain as nearly an average as possible, rep- resenting the coal as actually mined and shipped. It is a brilliant black, firm coal, with comparatively little fibrous coal or mineral charcoal. It cleaves readily into large rectangular blocks in mining. There is considerable pyrites mingled with it in an increasing ratio from the top to the bottom, the upper member carrying the least. A sample was taken from each member. The following analyses are by Dr. Peter and Mr. Talbutt, chemists of the Survey: 7 REPORT UPON THE ANALYSES OF NUMBER ELEVEN COAL, PARADISE MINE. Upper. Middle. Bottom Specific grasty.. 1.274 1.326 1-331 Moisture.. . 60 4.10 4.20 Volatile combustible matter. 38.70 35.90 36.io Fixed carbon . . . 53 70 coke 57 70 56o cke60. 00 5lcoke 59.70 Ash.......... 4(.00 57 6.4o e. 9.20j Total... .. .. .. soo.oo ioo.oo ioo.oo Sulphur..... .. .. 3.158 4.394 4.573 It will be seen from the above that while an extremely good coal in the matter of freedom from water and ash, yet there is a very considerable per centage of sulphur present. It is, however, an excellent household and steam coal, and is held in high repute wherever it has been tried. Large quantities are sent from the Paradise mines to Bowling Green, where it is used for domestic purposes and by the railroad, and it is there rated higher than any other coal from Green river. The No. 12 Coal.-As it was in the expectation of using this coal raw for fuel that the furnace was built, and as it was actually so used during the short campaigns of the furnace, it became a matter of considerable importance to obtain a per- fectly average representative sample for analysis. The attempt to obtain such a sample was only partially suc- cessful. The old entries by which the coal was worked have fallen in, so that it was impossible to get at the face of the coal where a sample from a number of places could be taken. A shaft was, therefore, sunk through the coal near one of the entries, and an average sample taken. Another was taken from a pile of several thousand bushels which lies at the mouth of one of the old drifts, where it has been exposed to the weather for seventeen years. Although these must both rep- resent the coal with a certain degree of accuracy, yet at both places it had been to a certain extent exposed to the weather, and may have absorbed water and parted with some sulphur. 168 AIRDRIE FURNACE AND PROPERTY. The fact that the coal is quite "e fat," however, containing much bituminous matter, tended to preserve it from the action of the weather. In the interior of the pile of coal at the entry many pieces were found only very slightly affected by its protracted e tposure. It is a deep -black coal, showing little pyrites, and quite bitu- minous, too much so apparently to be successfully used alone raw in the blast furnace. Of the following three analyses the first was made by Dr. Peter, and published in the fourth vol- ume of Kentucky Geological Reports, first series, page 230. Of the character of the sample and by whom taken I am ignorant. The second and third are by Dr. Peter and Mr. Talbutt, from average samples taken by myself. The second is the weathered coal from the stock-pile; the third from bot- tom of shaft near entry No. 4. ANALYSES OF NUMBER TWELVE COAL, AIRDRIE FURNACE. I. II. III. Specific gravity..... . 1'593 1.332 1.278 Moisture.............. 7.o6 40 7 3.60 Volatile c-mbustible matter. 30.84 30.60 31.40 Fixed carbon _. 7 e 58 8coke.64 7.50 coke 65,00 Total... .. .. . . 100.00 100.00 100.00 Sulphur. 0.789 1-455 1.438 A remarkable resemblance will be noticed between analyses two and three, showing that they have weathered very simi- larly; but the coal of No. 2 has absorbed more water and lost some of its volatile combustible matter. They show this to be a coal of very good quality, with neither sulphur nor ash sufficient to seriously injure it. It is so bituminous that it did not work well raw in the furnace, and after three unsuccessful trials it was decided to use it coked. A large amount of coke, s(ex fral thousand bushels, was made; but the furnace was never started again, and it now lies on the stock bank, some 169 9 REPORT UPON THE of it good looking coke yet, after the rain and snows of seven- teen years have fallen upon it. It is difficult to tell what the quality of it was when first made, and a sample taken from this pile does not fairly represent the coke that can be made from the coal; but it was regarded as matter of sufficient inter- est to be worth an analysis. I accordingly selected from the least weathered of the coke a sample for analysis, which is here given. The coke was made in open heaps, and there- fore is not as firm and dense as it would be if coked in close ovens: Moisture expelled at 212 ...................... ........... ............. 7.50 Moisture expelled at red heat .. ...... . . . . . . . ....... 4.20 Fixed caron .82.90 Ash .. . .. . . .. .. . .. .. ... ... ... .. . 5.4o Total... .. .. .. .. . .. .. .. . .. .. .. . .. .. .. tao.oo Sulphur.... .. .. . .. .. .. .. . .. .. .. . .. .. .. . o.642 The composition of the ash is as follows: Silica and silicates............... . 4.32 Alumina, oxide of iron, and manganese ..4 Lime.. .. . .. .. .. . .. .. .. .. . .. .. .. . .. .. . 33 Magnesia..... .. . .. .. .. .. . .. .. .. . .. .. .. . . i Phosphoric acid.. .8 Total. 539 As was to be expected, the coke has absorbed a very considerable per centage of water; but the amounts of both sulphur and ash are small. THE IRON ORE. Above the No. 12 Coal, already referred to, is a hard, dense, slaty carbonate, often containing fern leaf impressions between its cleavage planes. The amount of bituminous mat- ter shown by analysis is small, and probably adheres to it from the associate shale and coal. It contains occasional specks of pyrites large enough to be easily seen by the unassisted eye. Its appearance is decidedly against it, and it seems to be much leaner than it really is. 170 T0 AIRDRIE FURNACE AND PROPERTY. The same difficulty was experienced in obtaining a fair average sample of the ore as with the No. 12 Coal. A sample was obtained from the same shaft, sunk to reach the coal near the old No. 4 entry, but it was so near the surface that the ore had been altered to a limonite. At this place, too, it seemed to be less silicious than usual, and the average, of course, was taken from only a limited amount of ore. Another sample was taken from a pile of unroasted ore lying near the mouth of the entry, where it has been exposed to the weather for seventeen years. Still another sample was taken from a large pile of roasted ore, which had undergone a like period of exposure since roasting. In all of these there is a possibility that the ore is a little richer in iron and more free from sulphur than will be found to be the case when it is reached at a place where it is wholly unaltered; for the exposure to the air has a most bene- ficial effect in peroxidizing the iron and removing the sulphur. The analyses by Dr. Peter and Mr. Talbutt are as fol- lows: 1. 2. Peroxide of iron..... .. . .. .. . .. . .. .. . .. 63.048 859.810 Alumina... .. .. . .. .. . .. . .. .. . .. .. . 5.290 2.972 Brown oxide of manganese....9.0........... . .. g9 .720 Carbonateof lime. ... ......... .................. .50 Lime.. .... . .. . .. .. . .. .. . .. .. . . 2.263 Magnesia.. ...... . .. .. . .. . .. .. . .. . .9.930 4.270 Phosphoric acid...................... . .147 .223 Sulphur..... . . .. .. . .. .. . .. .. . .. .. .044 .o65 Combined water..... .. . .. . .. .. . .. .. . .. 12.430 .2o6 Silica and insoluble silicates........ .. . .. .. . . . 17-250 29.880 Total.. .. . .. .. . .. .. . .. . .. .. . .. . 99.909 100.409 Specific gravity......... 3.246 3.652 Metallic iron......... 44.133 41.867 Phosphorus.... .. . .. .. . .. .. . .. . .. .. . .064 .097 No. 1. Ore from bottom of shaft near No. 4 entry. No. 2. Roasted ore from the stock-pile, weathered seven- teen years since roasting. III I I REPORT UPON THE The above ores are both altered from the carbonate; one by the slow natural process of oxidation, the other by the process of roasting. The analyses of the carbonate ores: I.1 2. _ (carbonate of iron.............. . 47.810 59.344 Peroxideof iron..... . .. . .. .. . .. . .. . .. . 9.054 4.180 Alumina. .. .. . .. . .. . .. . .. .. . .. . .. . 5.205 2.290 Carte1nate of manganese.......... .. . .. . .. . . 797 2.017 Carbonate of lime......... . .. . .. .. . .. . . 3.740 3 390 Magnesia... .. . .. . .. . .. .. . .. . .. . .. . 7. 180 7.149 Phosphoric acid......... . . ...... . . . ... 179 .428 Sulphur.... . .. .. . .. . .. .. . .. . .. . .. . .094 .246 Carbonaceous matter and water........ . .. . .. . . 8.788 4.071 Silica and insoluble silicates.17.010 i6.2So Total... .. . .. . .. .. . .. . .. .. . .. . .. 100.099 oo. 6o9 Potash... . .. . .. . .. .. . .. . .. . .. . .. . .. . .. .286 Soda............ ..... ....... . 322 Specific gravity........... 3.376 2.959 Metallic iron............ 29.418 31-.598 Phosphorus... ..... .. .. . .. . .. . .. . .. . .078 .t 86 No. I. Average sample from the stock pile, where the ore had weathered seventeen years. No. 2. Analysis by Dr. Peter, published in volume three, page 337, of the first series Kentucky Geological Reports. of - Black-band ore, roof of upper coal, Airdrie Furnace." From the foregoing analyses the following conclusions are drawn: First. The No. II Coal, while a fine domestic and steam- producing fuel, contains too much sulphur to be used in the manufacture of iron, without a previous preparation by wash- ing and coking. That this could be successfully done there is little doubt. The strength and density of the coke might not be equal to the best, but it would be a fuel of fair quality; such as could, it is believed, be used successfully in the manufacture of iron. Second. The No. 12 Coal is an excellent fuel, on account of its small per centages of sulphur and ash; but the former experience of the furnace seems to prove conclusively what 172 12 AIRDRIE FURNACE AND PROPERTY. the appearance of the coal indicates, that it is too fat to use raw in the furnace, and should be coked. The amount of sulphur is so small that the coal can be coked without previ- ous preparation, to free it from sulphur, and it will probably produce a superior coke; this, however, can only be dem- onstrated by actual trial on a large scale. Third. The ore contains enough iron and is sufficiently free from injurious mixture to be safely used to a certain extent; but it will probably prove necessary to use other ores with it. It is not unlikely, as already stated, that the analyses rep- resent the ore as somewhat better than it really is, and that it will be found on trial, when used alone, to make a low grade of iron. There is, furthermore, the fact that, while both the coal and ore have to be mined together in order to be cheaply obtained, the output of coal for a given area will be more than twice as much as is required for the reduction of the ore from the same area, assuming from the general testimony that the coal will average two feet in thickness and the ore six inches. Of the coal, with a specific gravity of 1.33 and a thickness of two feet, each acre of land will contain 3,300 tons of 2,240 pounds each. Of the ore, with a specific gravity of 3.25, and six inches thick, each acre will contain 2,015 tons. The ore will prob- ably not yield in the furnace more than an average of twenty- eight or twenty-nine per cent., thus requiring for the production of one ton of iron three and a half tons of the raw ore. For the reduction of this amount of ore only from two to three gross tons of coal will be required, probably not exceeding an average of two and a half tons. The coal from one acre of land will, therefore, be sufficient for the reduction of more than two and a fifth times as much ore as is produced from the same area. The necessity, then, of looking elsewhere for a partial ore supply is evident. The situation of Airdrie Furnace is one remarkably favor- able for the facilities with which ores from a number of regions can be cheaply laid down at the furnace. It can command, at very reasonable rates for freight, the following ores: 173 I13 14 REPORT UPON THE (a) Coal measure ores from Green river valley. (b) Limonites from the Cumberland river region. (c) Specular ores from Missouri. (a) Coal measure ores from the Green river valley. There are, in a large number of places in the valley of Green river, ores of workable thickness and apparently considerable area; but they are as yet generally undeveloped, and frequently so far from the river or other means of transportation that they cannot be rendered available without the expenditure of con- siderable sums to provide such means of transportation. To this class belong the ores of the Buckner Furnace tract,already referred to. These must some day be developed and used at the furnace; but for the present they are inaccessible. They comprise both slaty carbonates or Black-band, and fossiliferous ores. One locality was visited where is an exposure of eight or ten inches of the Black-band ore, and a sample for analysis selected. The ore from which it was taken had been ex- posed to the weather for thirty years or more. The following is the analysis by Dr. Peter and Mr. Talbutt: Carbonate of iron ............. ............ . . 42. 95 Peroxide of iron ............. . ............... . 29.60S Alumina........ .. .. . .. .. .. . .. .. .. ....... . 2.454 Carbonate of manganese.. I.S3 Carbonate of lime. 2 90 Carbonate of magnesia............... ....... 4. S28 Phosphoric acid... .... . . . , .085 Sulphuricacid..... .. . .. .. .. . .. .. .. .. . l.5 l. i Carbonaceous matter and loss. 5.8 Silica and insoluble silicates. 9030 Total . ........ . ............100.000 Metallic iron. . . ... . . . . . . . 36.g96 Phosphorus.... .. . .. .. .. . .. .. .. .. . ... .. .. .036 Sulphr...... .. .. .. .. . .. .. .. . .. .. . .. .. .. . .638 In Edmonson county, on the north side of Green river, between Bear Creek and Nolin river, is an extensive and val- uable deposit of o6litic ore; but it is, where best developed, some six miles from Green river, and it cannot be hauled to the river cheaply enough to compete with ores from other 174 AIRDRIE FURNACE AND PROPERTY. '5 places lower down. It is of excellent quality, and can be mined quite cheaply, and, if accessible, would be one of the most available ores. I append analysis, by Dr. Peter and Mr. Talbutt, of ore from a bank at the head of Beaver Dam Branch of Bear Creek. Shaler: Average sample by Prof. N. S. Peroxide of iron....... .. . .. . .. . .. . .. . .. . . . . 52.926 Alumina.. . . . . .. . .. . .. . .. . .. . . .. . .. . .. 4.792 Brown oxide of imanganese... .. . .. . .. . .. . . .. . .. . . .210 Carbonate of.. . . .. . . .. . .. . .. . .. . . .. . .. . . . ISO Magnesia.., 42S Phosphoric acid .35S Sulphur.... . . ..057 Combined water..... ................................ .. 10.400 Silica and insoluble silicates.... . .. . . .. . .. . .. . . .. . . 30.589 Total... . .. . .. . .. . .. . . .. . .. . .. . .. . .. . 99934 Metallic iron..... ..... ..........37.048 Phosphorus... .. . .. . .. . . .. . .. . .. . . .. . .. . . 15 In Butler county, near the mouth of Little Reedy Creek, from one and a half to two miles distant from Green river, on the James E. Taylor farm, is a deposit of ore which shows at the outcrop three feet thick. It was only seen at one place, and little or nothing is known of its horizontal range. It has never been worked. An average sample was taken by Mr. J. R. Proctor, who first discovered it, and analyzed by Dr. Peter and Mr. Talbutt, with the following result: Peroxide of iron........ . . .. . .. . .. . .. . .. . . . 48.049 Alumina. . . .. . .. . . .. . .. . .. . .. . .. . . . 8.171 Brown oxide of manganese.... . .. . .. . . .. . I. . .. . .. .140 Carbonate of lime... .. . .. . .. . .. . .. . . .. . .. . .. . 540 Magnesia... . .. . .. . .. . .. . .. . . .. . .. . .. . .. . 195 Phosphoric acid........................... 5 Sulphuric acid....... . .. . . . . .473 Combined water.... .. . .. . .9....... . .. . . .. . . . 9.750 Silica and insoluble silicates.3..9................... . _ 9_ Total... . .. . .. . .. . .. . .. . .. . . .. . .. . .. . 99563 Metallic iron..... ........................ . 33.634 Phosphorus... .. . .. . .. . .. . . .. . .. . .. . .. . .. .150 Sulphur.... . .. . .. . ... . . . .. . ... .. . .. . . . .189 175 REPORT UPON THE It is a silicious, somewhat oolitic limonite, altered from the carbonate; and as it occurs in shales, with a high hill above it, it will probably be soon found as the blue carbonate. Its situation is such that it can be very cheaply placed in boats, on the slack-water of Green river, about seven miles above the lock at Woodbury. Should it be found, on closer examination, to retain its thickness, and extend over a consid- erable area, it can be mined very cheaply. A reasonable estimate of its cost at the furnace, provided the above conditions hold, would be: Per ton. Mining and royalty....................................... . 175 Hauling to river and loading on barges......... .. . .. .. . . 75 Freight on Green river.................. . . 1 25 Unloading at furnace.......... . .. .. .. . .. .. . .. . 25 Making the total cost......... .. .. .. .. .. . .. .. . 4 oo Two of these items, the freight on Green river and the hauling to the river, might be considerably reduced. It is probable that three dollars or three dollars and fifty cents would be a minimum cost at the furnace. In Muhlenburg county, on Mud river, on land belonging to Jeremiah M. Hope, is a deposit of ore which, over a limited area, shows the unusual thickness of twelve to fifteen feet. The ore is exceedingly fossiliferous, partly a limonite and partly an unaltered carbonate. The upper portion of the ore is somewhat lean and silicious; the middle and lower portions of the bed are of fine quality. The following analyses by Dr. Peter and Mr. Talbutt show the character of the ore: 176 AIRDRIE FURNACE AND PROPERTY. 17 1. 2. 3- Peroxide of iron........... . . .. . . 46.866 60.492 18-374 Carbonate of iron . . ... .. ...... 26.643 Alumina.5... .. . .. .. . . . . . .. , 5930 7.075 6.548 Brown oxide of manganese............ . .103 .360 a trace. (arb.nate of lime............... . . 2.535 1.980 13.430 Magnesia... ..... . .. ,..... .. . . 1x073 1. 550 5.698 Phosphoric acid..... . .. .. .. . .179 .o83 .211 Sulphur... . .. . 0.... .. . .. .. . . .059 .074 .074 combined water.......... . .. . .. . . 9. 550 12. 530 6. 792 silica and insoluble silicates ............ . 33.530 15.560 22.230 Total... .. . .. . .. . 9...... . . 9.825 99.674 . kfetatlic iron.3........ .. .. . .. . . . 32.8o6 42.344 27.136 Phosphorus.n...... . .. .. . .. . .. . . 0`77 .032 .092 i. Sample, not carefully averaged, of limonite from the upper portion of the deposit. 2. Average sample of the lirnonite of the lower and middle portions of the deposit. 3. Average sample of the blue carbonate ore of the lower part of the deposit. This ore seems to be in a regularly stratified deposit, but it only retains its unusual thickness over an area of perhaps 1,200 square yards. It is found at another locality, one third of a mile distant, on the opposite side of the ridge, two and a half feet thick. The distance of the principal deposit from the head of slack-water, on Mud river, is four miles. Over this distance the ore would have to be wagoned, at a probable cost of one dollar and fifty cents per ton. The distance from the head of navigation, on Mud river, to Airdrie, by water, is about twenty miles, and in that twenty miles one lock to be passed. The cost of freight would be about seventy-five cents per ton. The ore can be mined quite cheaply, as very little stripping will be required for some time. One dollar and twenty-five cents will probably be sufficient to cover the cost of mining and royalty. The cost of this ore would therefore be: VIL 11-12 REPORT UPON THE Per ton. Mining and royalty........................ .. 25 Hauling to river. 50 Freight to Airdrie .75 Unloading at furnace .25 Total. 3 75 By the purchase of the deposit and the use of their own barges by the owners of the furnace, this cost might be reduced to three dollars, or even less. In Muhlenburg county, near Greenville, on the farm of Mr. Dabney Martin, some three miles from the Louisville, Paducah and Southwestern Railroad, is a bed of quite pure limonite ore. It is only eight inches thick, but is so situated that it could be mined over a large area, as the stripping above it would not be deep. It is of excellent quality. The analysis is as follows: Peroxide of iron....... .. .. .. . .. . .. . .. . .. .. . 69.546 Alumina............................... . 3.914 Brown oxide of manganese....... .. .. . .. . .. .. . .. . .2p0 Carbonate of lime........ .. . .. . .. .. . .. . .. . .480 Magnesia.. .. .. . .. . .. . .. .. . .. . .. . .. .. . .. .921 Phosphoric acid.... .. . ..